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It is based on the fact that some of the radioactive isotope of Potassium, Potassium-40 (K-40) ,decays to the gas Argon as Argon-40 (Ar-40).By comparing the proportion of K-40 to Ar-40 in a sample of volcanic rock, and knowing the decay rate of K-40, the date that the rock formed can be determined.Time since recrystallization is calculated by measuring the ratio of the amount of The quickly cooled lavas that make nearly ideal samples for K–Ar dating also preserve a record of the direction and intensity of the local magnetic field as the sample cooled past the Curie temperature of iron.The geomagnetic polarity time scale was calibrated largely using K–Ar dating.The calcium-potassium age method is seldom used, however, because of the great abundance of nonradiogenic calcium in minerals or rocks, which masks the presence of radiogenic calcium.On the other hand, the abundance of argon in the is relatively small because of its escape to the atmosphere during processes associated with volcanism.Potassium can be mobilized into or out of a rock or mineral through alteration processes.Due to the relatively heavy atomic weight of potassium, insignificant fractionation of the different potassium isotopes occurs.

Coins found in excavations may have their production date written on them, or there may be written records describing the coin and when it was used, allowing the site to be associated with a particular calendar year.

Potassium is a common element found in many materials, such as micas, clay minerals, tephra, and evaporites.

In these materials, the decay product Ar is able to escape the liquid (molten) rock, but starts to accumulate when the rock solidifies (recrystallizes).

Potassium-Argon Dating Potassium-Argon dating is the only viable technique for dating very old archaeological materials.

Geologists have used this method to date rocks as much as 4 billion years old.

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